Improving the performance of a poorly adsorbing porous material: template mediated addition of microporosity to a crystalline submicroporous MOF.
نویسندگان
چکیده
The presence of butanoic acid excess in the reaction media employed for the synthesis of a MOF with formula [Cu(2)(μ(3)-ade)(2)(μ(2)-OOC(CH(2))(2)CH(3))(2)](n) (ade: adeninate) leads to the formation of micelles that exert a template effect and provide a pronounced increase of its microporosity, doubling the intrinsic adsorption capacity of the pristine crystal network.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 6 شماره
صفحات -
تاریخ انتشار 2012